The internal combustion engine is an engine in which the combustion of a fuel (normally a fossil fuel) occurs with an oxidizer (usually air) in a combustion chamber. In an internal combustion engine the expansion of the high-temperature and -pressure gases produced by combustion applies direct force to some component of the engine, such as pistons, turbine blades, or a nozzle. This force moves the component over a distance, generating useful mechanical energy.

The term internal combustion engine usually refers to an engine in which combustion is intermittent, such as the more familiar four-stroke and two-stroke piston engines, along with variants, such as the Wankel rotary engine. A second class of internal combustion engines use continuous combustion: gas turbines, jet engines and most rocket engines, each of which are internal combustion engines on the same principle as previously described.

The internal combustion engine (or ICE) is quite different from external combustion engines, such as steam or Stirling engines, in which the energy is delivered to a working fluid not consisting of, mixed with, or contaminated by combustion products. Working fluids can be air, hot water, pressurized water or even liquid sodium, heated in some kind of boiler.

A large number of different designs for ICEs have been developed and built, with a variety of different strengths and weaknesses. Powered by an energy-dense fuel (which is very frequently petrol, a liquid derived from fossil fuels), the ICE delivers an excellent power-to-weight ratio with few disadvantages. While there have been and still are many stationary applications, the real strength of internal combustion engines is in mobile applications and they dominate as a power supply for cars, aircraft, and boats, from the smallest to the largest. Only for hand-held power tools do they share part of the market with battery powered devices

An external combustion engine (EC engine) is a heat engine where an (internal) working fluid is heated by combustion of an external source, through the engine wall or a heat exchanger. The fluid then, by expanding and acting on the mechanism of the engine produces motion and usable work.[1] The fluid is then cooled, compressed and reused (closed cycle), or (less commonly) dumped, and cool fluid pulled in (open cycle air engine).

“Combustion” refers to burning fuel with an oxidizer, to supply the heat. Engines of similar (or even identical) configuration and operation may use a supply of heat from other sources such as nuclear, solar, geothermal or exothermic reactions not involving combustion; but are not then strictly classed as external combustion engines, but as external thermal engines.

The working fluid can be a gas as in a Stirling engine, or steam as in a steam engine. The fluid can be of any composition; gas is by far the most common, although even single-phase liquid is sometimes used. In the case of the steam engine, or the Organic Rankine Cycle the fluid changes phases between liquid and gas.

In thermodynamics, a heat engine performs the conversion of heat energy to mechanical work by exploiting the temperature gradient between a hot “source” and a cold “sink”. Heat is transferred from the source, through the “working body” of the engine, to the sink, and in this process some of the heat is converted into work by exploiting the properties of a working substance (usually a gas or liquid).

Heat engines are often confused with the cycles they attempt to mimic. Typically when describing the physical device the term ‘engine’ is used. When describing the model the term ‘cycle’ is used.

In thermodynamics, heat engines are often modeled using a standard engineering model such as the Otto cycle. The theoretical model can be refined and augmented with actual data from an operating engine, using tools such as an indicator diagram. Since very few actual implementations of heat engines exactly match their underlying thermodynamic cycles, one could say that a thermodynamic cycle is an ideal case of a mechanical engine. In any case, fully understanding an engine and its efficiency requires gaining a good understanding of the (possibly simplified or idealized) theoretical model, the practical nuances of an actual mechanical engine, and the discrepancies between the two.

In general terms, the larger the difference in temperature between the hot source and the cold sink, the larger is the potential thermal efficiency of the cycle. On Earth, the cold side of any heat engine is limited to being close to the ambient temperature of the environment, or not much lower than 300 Kelvin, so most efforts to improve the thermodynamic efficiencies of various heat engines focus on increasing the temperature of the source, within material limits. The maximum theoretical efficiency of a heat engine (which no engine ever obtains) is equal to the temperature difference between the hot and cold ends divided by the temperature at the hot end, all expressed in absolute temperature or kelvins.

The efficiency of various heat engines proposed or used today ranges from 3 percent (97 percent waste heat) for the OTEC ocean power proposal through 25 percent for most automotive engines, to 45 percent for a supercritical coal plant, to about 60 percent for a steam-cooled combined cycle gas turbine.

All of these processes gain their efficiency (or lack thereof) due to the temperature drop across them.